A library of complexes exhibit reaction

The second meeting was held at the Butcher’s Inn on December 4, 1959. A resolutions committee, comprised of Evans, Goodfellow, Tompkins and Sherf (as chairman), presented the resolution to form what was to be known as the Red Wings Alumni Club. The resolution was passed unanimously.

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Firstly, a trifluoromethylation protocol is described, which uses a [RuCp]+ binding unit to activate a range of electron deficient arenes towards the nucleophilic attack of commercially available Me3SiCF3 (Ruppert’s Reagent). A library of complexes exhibit reaction, and a mixture of products are formed via SNAr and ortho addition mechanisms. Following trifluoromethylation, the unbound arenes can be collected in quantitative yield using photolysis and chemical oxidation.

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